• 文献标题:   Poly(ionic liquids) functionalized polypyrrole/graphene oxide nanosheets for electrochemical sensor to detect dopamine in the presence of ascorbic acid
  • 文献类型:   Article
  • 作  者:   MAO H, LIANG JC, ZHANG HF, PEI Q, LIU DL, WU SY, ZHANG Y, SONG XM
  • 作者关键词:   poly ionic liquids pils, polypyrrole ppy, graphene oxide go, dopamine da, ascorbic acid m, electrochemical sensor
  • 出版物名称:   BIOSENSORS BIOELECTRONICS
  • ISSN:   0956-5663 EI 1873-4235
  • 通讯作者地址:   Liaoning Univ
  • 被引频次:   77
  • DOI:   10.1016/j.bios.2015.03.059
  • 出版年:   2015

▎ 摘  要

Novel poly(ionic liquids) functionalized polypyrrole/graphene oxide nanosheets (PILs/PPy/GO) were prepared by the polymerization of 1-vinyl-3-ethylimidazole bromide (VEIB) on the surface of N-vinyl imidazolium modified PPy/GO nanosheets. Due to the synergistic effects of GO with well-defined lamellar structures, conductive PPy and biocompatible PILs, PILs/PPy/GO modified glassy carbon electrode (GCE) presented the excellent electrochemical catalytic activity towards dopamine (DA) with good stability, high sensitivity and wide linear range in the present of ascorbic acid (AA) with high concentration. PILs played an essential role for the simultaneous determination of DA and AA in a mixture, whose existence effectively improved the transmission mode of electrons and resulted in the different electrocatalytic performance towards the oxidation of DA and AA. It is indicated that PILs/PPy/GO nanosheets can act as a good steady and sensitive electrode material for the development of improved DA sensors. (C) 2015 Elsevier B.V. All rights reserved.