• 文献标题:   Tailored Synthesis of Various Nanomaterials by Using a Graphene-Oxide-Based Gel as a Nanoreactor and Nanohybrid-Catalyzed C-C Bond Formation
  • 文献类型:   Article
  • 作  者:   BISWAS A, BANERJEE A
  • 作者关键词:   crosscoupling, graphene, nanoparticle, nanoreactor, vitamin
  • 出版物名称:   CHEMISTRYAN ASIAN JOURNAL
  • ISSN:   1861-4728 EI 1861-471X
  • 通讯作者地址:   Indian Assoc Cultivat Sci
  • 被引频次:   10
  • DOI:   10.1002/asia.201402695
  • 出版年:   2014

▎ 摘  要

New graphene oxide (GO)-based hydrogels that contain vitaminB(2)/B-12 and vitaminC (ascorbic acid) have been synthesized in water (at neutral pH value). These gel-based soft materials have been used to synthesize various metal nanoparticles, including Au, Ag, and Pd nanoparticles, as well as nanoparticle-containing reduced graphene oxide (RGO)-based nanohybrid systems. This result indicates that GO-based gels can be used as versatile reactors for the synthesis of different nanomaterials and hybrid systems on the nanoscale. Moreover, the RGO-based nanohybrid hydrogel with Pd nanoparticles was used as an efficient catalyst for CC bond-formation reactions with good yields and showed high recyclability in Suzuki-Miyaura coupling reactions.