• 文献标题:   Thermoelectric properties of unoxidized graphene/Bi2Te2.7Se0.3 composites synthesized by exfoliation/re-assembly method
  • 文献类型:   Article
  • 作  者:   KIM JI, LEE ES, KIM JY, CHOI SM, LEE KH, SEO WS
  • 作者关键词:   thermoelectric propertie, bismuth telluride, graphene, exfoliation
  • 出版物名称:   PHYSICA STATUS SOLIDIRAPID RESEARCH LETTERS
  • ISSN:   1862-6254 EI 1862-6270
  • 通讯作者地址:   Korea Inst Ceram Engn Technol
  • 被引频次:   5
  • DOI:   10.1002/pssr.201308321
  • 出版年:   2014

▎ 摘  要

Nanocomposites of n-type thermoelectric Bi2Te2.7Se0.3 (BTS) and unoxidized graphene (UG) were prepared from the exfoliated BTS and UG nanoplatelets. Polycrystalline BTS ingots were exfoliated into nanoscoll-type crystals by chemical exfoliation, and were re-assembled with UG nanoplatelets. The composites were chemically reduced by hydrazine hydrate and sintered by a spark-plasma-sintering method. The thermoelectric properties of the sintered composites were evaluated and exhibited decreased carrier concentration and increased thermal conductivity due to the embedded graphene. The peak ZT values for the UG/BTS-US and UG/BTS-EX composites were approximate to 0.8 at the UG concentration of 0.05 wt%. ((c) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)