• 文献标题:   Preparation and characterization of polysulfone/ammonia-functionalized graphene oxide composite membrane material
  • 文献类型:   Article
  • 作  者:   IONITA M, PANDELE AM, CRICA LE, OBREJA AC
  • 作者关键词:   polysulfone, ammoniafunctionalized graphene oxide, nanocomposite, membrane material, mechanical strength
  • 出版物名称:   HIGH PERFORMANCE POLYMERS
  • ISSN:   0954-0083 EI 1361-6412
  • 通讯作者地址:   Univ Politehn Bucuresti
  • 被引频次:   8
  • DOI:   10.1177/0954008315576233
  • 出版年:   2016

▎ 摘  要

The study highlights the first use of ammonia-functionalized graphene oxide (GO-NH2) as an additive to enhance the features of polysulfone (PSF) matrix. Composite membrane materials with different ratios of GO-NH2 (0.25, 0.5, 1, and 1.5 wt%) were obtained by phase inversion method. Subsequently structural and morphological characteristics were investigated by Raman spectroscopy, X-ray diffraction (XRD), scanning, and transmission electron microscopy (TEM). Lastly, mechanical and thermogravimetric studies were performed in order to establish whether GO-NH2 addition influenced PSF/GO-NH2 composite material performance. Raman spectroscopy, XRD, and TEM revealed evenly dispersed GO-NH2 within PSF/GO-NH2 composite membrane material forming exfoliated structures for lower concentration of GO-NH2. An enhancement in both mechanical and thermal characteristics was attained. The decomposition temperature at which the mass loss is 3%, of the composite membrane material with 1 wt% GO-NH2 was increased with 7 degrees C. Conversely, an increase in Young's modulus from 246 MPa to 285 MPa was achieved with the addition of 1 wt% GO-NH2 within the PSF matrix.