• 文献标题:   Electropolymerization of a conductive beta-cyclodextrin polymer on reduced graphene oxide modified screen-printed electrode for simultaneous determination of ascorbic acid, dopamine and uric acid
  • 文献类型:   Article
  • 作  者:   QIN Q, BAI X, HUA ZL
  • 作者关键词:   reduced graphene oxide, electropolymerization, conductive betacyclodextrin polymer, ascorbic acid, uric acid, dopamine
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Hohai Univ
  • 被引频次:   29
  • DOI:   10.1016/j.jelechem.2016.10.004
  • 出版年:   2016

▎ 摘  要

This work introduces an electrochemical sensor fabricated by electropolymerization of a conductive beta-cyclodextrin (beta-CD) polymer onto a reduced graphene oxide (rGO)-decorated screen-printed electrode (SPE). The coated beta-CD polymer had a high supramolecular recognition capability and superior electrical conductivity, which can improve the electrochemical properties of the beta-CD/rGO/SPE electrode. Electrochemical behaviors of ascorbic acid (AA), dopamine (DA), and uric acid (UA) on the beta-CD/rGO/SPE electrode were investigated by cyclic voltammetry and differential pulse voltammetry. The anodic peaks of these three molecules were separated perfectly at the sensor, indicating that the beta-CD/rGO/SPE electrode can simultaneously detect these three molecules. The linear ranges for AA, DA and UA were 0.2-2 mM, 0.05-50 mu M and 0.08-150 mu M, respectively. The corresponding detection limits were 0.067 mM, 0.017 mu M and 0.026 mu M, respectively. As a practical application, the proposed sensor was successfully applied to quantify the concentrations of AA, DA and UA in real biological samples. These results demonstrate that this beta-CD/rGO/SPE electrode can be a promising electrochemical sensor for electrocatalytic applications. (C) 2016 Elsevier B.V. All rights reserved.