• 文献标题:   Photoluminescence mechanism in graphene quantum dots: Quantum confinement effect and surface/edge state
  • 文献类型:   Article
  • 作  者:   ZHU SJ, SONG YB, WANG J, WAN H, ZHANG Y, NING Y, YANG B
  • 作者关键词:   graphene quantum dot, photoluminescence mechanism, quantum confinement effect, surface state, carbon dot
  • 出版物名称:   NANO TODAY
  • ISSN:   1748-0132 EI 1878-044X
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   78
  • DOI:   10.1016/j.nantod.2016.12.006
  • 出版年:   2017

▎ 摘  要

As a new class of fluorescent carbon materials, graphene quantum dots (GQDs) have drawn increasing attention due to their outstanding properties and potential applications. Herein, GQDs prepared by chemical synthetic strategies, which mainly contain cutting different carbon resources and carbonization from small molecules or polymers, are discussed. Although the photoluminescence (PL) mechanism of GQDs can be explained by the size of the GQDs, surface chemical groups, and doping atoms, there is no universal agreement on the specific PL mechanism. The dominant PL mechanism of GQDs consists of the quantum confinement effect of conjugated pi-domains, the surface/edge state in GQDs, as well as the synergistic effect of these two factors. (C) 2016 Elsevier Ltd. All rights reserved.