• 文献标题:   Photoluminescence and band gap modulation in graphene oxide
  • 文献类型:   Article
  • 作  者:   LUO ZT, VORA PM, MELE EJ, JOHNSON ATC, KIKKAWA JM
  • 作者关键词:   energy gap, graphene, photoluminescence, reduction chemical
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Univ Penn
  • 被引频次:   403
  • DOI:   10.1063/1.3098358
  • 出版年:   2009

▎ 摘  要

We report broadband visible photoluminescence from solid graphene oxide, and modifications of the emission spectrum by progressive chemical reduction. The data suggest a gapping of the two-dimensional electronic system by removal of pi-electrons. We discuss possible gapping mechanisms, and propose that a Kekule pattern of bond distortions may account for the observed behavior.