• 文献标题:   Graphene functionalized attapulgite/sulfur composite as cathode of lithium-sulfur batteries for energy storage
  • 文献类型:   Article
  • 作  者:   XIE QX, ZHENG AR, XIE C, FU WG, WU SH, ZHANG YF, ZHAO P
  • 作者关键词:   lithiumsulfur battery, attapulgite, cathode, composite, graphene
  • 出版物名称:   MICROPOROUS MESOPOROUS MATERIALS
  • ISSN:   1387-1811 EI 1873-3093
  • 通讯作者地址:   Tianjin Polytech Univ
  • 被引频次:   9
  • DOI:   10.1016/j.micromeso.2015.11.049
  • 出版年:   2016

▎ 摘  要

Graphene nanosheets (GNs) functionalized attapulgite (ATTP)/sulfur (ATTP@GNs/S) composites were prepared through the melt-diffusion method, and investigated as cathode of lithium sulfur (Li-S) batteries. Owing to the strong adsorption capability and sulfur/lithium polysulfides (Li2Sn) confinement of the natural ATTP nanofibers and partially reduced GNs, ATTP/S and ATTP@GNs/S exhibit improved electrochemical performance compared to elemental sulfur. The ATTP@GNs/S composite shows an initial discharge capacity of 1143.9 mAh g(-1), and a reversible capacity of ca. 512.0 mAh g(-1) after 100 cycles at 0.1 C, giving a capacity decay rate of as low as 0.5% per cycle. This research demonstrates the possibility of utilizing ATTP as sulfur host matrix or as cathode additives for enhanced energy storage capability of Li-S batteries. (C) 2015 Elsevier Inc. All rights reserved.