• 文献标题:   Facile synthesis of CoNi2S4/graphene nanocomposites as a high-performance electrode for supercapacitors
  • 文献类型:   Article
  • 作  者:   LIN JJ, YAN S, LIU P, CHANG X, YAO L, LIN HL, LU DL, HAN S
  • 作者关键词:   coni2s4/graphene, supercapacitor, high specific capacitance, asymmetric electrode
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Shanghai Inst Technol
  • 被引频次:   3
  • DOI:   10.1007/s11164-018-3400-6
  • 出版年:   2018

▎ 摘  要

CoNi2S4/graphene nanocomposites were synthesized by a simple solvothermal method and used as supercapacitor electrodes. CoNi2S4 nanoparticles were doped in graphene layers, which is favorable for improving electrochemical performances of the as-prepared materials. The resulting electrochemical performance of CoNi2S4/graphene nanocomposite electrodes possessed pseudocapacitive behavior with high specific capacitance (1621 F g(-1) at 0.5 A g(-1)), good rate capability (76.7% capacitance retention when reaching 10 A g(-1)) and outstanding cycling stability (no capacitance loss after 2500 charge-discharge cycles at 5 A g(-1)). In addition, as the positive electrode of an asymmetric supercapacitor, the material also shows a high specific capacitance of 126.6 F g(-1) at 0.5 A g(-1), good cycle stability with capacitance retention of 87.4% after 5000 cycles and the highest energy density of 39.56 W h kg(-1) at the power density of 374.8 W kg(-1).