• 文献标题:   Pd-Mn3O4 on 3D hierarchical porous graphene-like carbon for oxygen evolution reaction
  • 文献类型:   Article
  • 作  者:   ZHANG CJ, PAN GL, ZHOU YQ, XU CW
  • 作者关键词:   oxygen evolution, water oxidation, graphenelike carbon, palladium, manganese oxide
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Guangzhou Univ
  • 被引频次:   3
  • DOI:   10.1007/s11581-018-2435-4
  • 出版年:   2018

▎ 摘  要

A 3D hierarchical porous graphene-like carbon (3D HPG) has been studied as conducting support for Pd and Mn3O4 nanoparticles. The Pd-Mn3O4 supported on 3D HPG demonstrates as an excellent catalyst for oxygen evolution reaction (OER) in alkaline medium. The Pd-Mn3O4(wt 2:1)/HPG catalyst shows a low onset potential of 0.497 V and achieves a high current density of 5.3 mA cm(-2) at 0.7 V (vs. SCE). The outstanding electrocatalytic activity is attributed to a synergistic effect between Pd and Mn3O4, and the 3D HPG enhances conductivity for charge transport and gives more active sites for the OER reaction.