• 文献标题:   Surface functionalization of graphene oxide with DBU as electrode materials for supercapacitors
  • 文献类型:   Article
  • 作  者:   ZHANG X, QU N, FAN QY, YANG H
  • 作者关键词:   graphene oxide, dbu, functionalization, nitrogencontaining, supercapacitor
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Dalian Univ Technol
  • 被引频次:   2
  • DOI:   10.1088/2053-1591/ab1a25
  • 出版年:   2019

▎ 摘  要

Nitrogen-containing groups functionalized graphene has been synthesized via the reaction of graphene oxide with 1, 8-diazoicyclo (5, 4, 0) undecene-7, trimethylamine (DBU) through epoxide-ring-open reaction without high temperatures. Samples were analyzed by x-ray diffraction spectroscopy, Raman, N-2 adsorption-desorption, transmission electron microscope, galvanostatic charge/discharge, and cyclic voltammetrys. Results show that the amount of added DBU has great influence on the structure and properties of the resultant graphene. The DBU modified graphene with appropriate N content and low charge transfer resistance exhibits 190 F g(-1) at 5 mV s(-1) in 6 M KOH aqueous solution. This will also provide a new strategy for configuring nitrogen-containing groups functionalized graphene electrode materials for supercapacitors and other energy storage devices.