▎ 摘　　要

Robust porous SiO2/Si/graphene/C microspheres have been successfully synthesized by a simple two-step process of ultrasonic spraying and partial magnesiothermic reduction. The 3-D porous microspheres consist of Si/SiO2 nanoparticles (around 5-10 nm) covered by a layer of carbon and connected by graphene. We explored the electrochemical properties of the porous microspheres as an anode for lithium ion batteries (LIBs). In SiO2/Si/graphene/C microspheres, numerous pores could leave enough room for volume expansion and contraction of silicon during lithiation and delithiation, and provide large space voids for electrolyte reserves. Meanwhile, graphene plays a role in reinforcing the porous structure. The prepared sample shows superior cyclability with a discharge capacity of 1104.9 mA h g(-1) in the second cycle and 1141.6 mA h g(-1) over 200 cycles at a current density of 0.1 mA cm(-2). The capacity retention is more than 100%, making it very promising as a future LIBs anode.