• 文献标题:   Industrial waste reuse: An alternative source to reduced graphene oxide for preparing electrochemical sensors
  • 文献类型:   Article
  • 作  者:   MELO JF, JUNIOR JHS, FREIRE TBD, RIGOTI E, PERGHER SBC, MARTINEZHUITLE CA, CASTRO PS
  • 作者关键词:   recycledrgo, paracetamol determination, electrochemical sensor, real sample, reuse of industrial waste
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.electacta.2023.142382 EA APR 2023
  • 出版年:   2023

▎ 摘  要

Development of sustainable electroanalytical platforms based on recovering approaches has great importance, once that they aim to minimize waste and increase reusing/recycling efforts, as well as engage the circular economy. This work converted an industrial waste carbon source to a recycled reduced graphene oxide (r-rGO) using a cost effective wide scale synthesis. The r-rGO was characterized by SEM, XRD, FTIR, and Raman spec-troscopy techniques and as a proof-of-concept the new material was applied as electrode modifier for paracet-amol (PAR) electroanalytical determination in tablets. The simple, easy and rapid technique of drop casting a suspension solution of r-rGO, was used to prepare the surface of a chemically modified glassy carbon electrode (GCE) forming a r-rGO/GCE sensor. Differential pulse voltammetry (DPV) was optimized and applied success-fully in the paracetamol determination with a linear range of 60-500 mu mol L-1 and detection limit of 0.28 mu mol L-1. Then, two commercialy avaliable paracetamol tablets were used, with a minimum sample preparation, achieving recoveries of 99.43% and 100.47%. A HPLC (high performance liquid chromatography) comparative method was performed obtaining recoveries of 100.92% and 101.00%. Finally, the obtained results demonstrate that the r-rGO/GCE sensor can be a promising alternative for the quantitative determination of PAR in phar-maceutical formulations.