▎ 摘 要
A three-dimensional ZnO/graphene/CNT (carbon nanotube) composite was prepared by a one-step sol-gel synthetic technique followed by vacuum-assisted filtration. High resolution transmission electron microscopy revealed the formation of highly-dispersed ZnO nanoparticles, uniformly laid on the crumpled graphene sheets and CNT. The as-prepared ZnO/graphene/CNT composite exhibited excellent cyclability and rate capability when used as anode for lithium ion batteries, affording 620 mAh g(-1) stable reversible discharge capacity after 100 cycles at 100 mA g(-1). The unique composite structure provided a large surface area and highly conductive network which maintains good electronic contact between particles, suppresses ZnO aggregation during the charge/discharge processes, and accommodates the large volume changes of ZnO upon cycling. (C) 2016 Elsevier B.V. All rights reserved.