• 文献标题:   Simple fabrication of free-standing ZnO/graphene/carbon nanotube composite anode for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG YG, WEI YQ, LI HP, ZHAO Y, YIN FX, WANG X
  • 作者关键词:   lithium ion battery, anode, zno/graphene/cnt composite, freestanding, nanoparticle, energy storage conversion
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Hebei Univ Technol
  • 被引频次:   22
  • DOI:   10.1016/j.matlet.2016.08.017
  • 出版年:   2016

▎ 摘  要

A three-dimensional ZnO/graphene/CNT (carbon nanotube) composite was prepared by a one-step sol-gel synthetic technique followed by vacuum-assisted filtration. High resolution transmission electron microscopy revealed the formation of highly-dispersed ZnO nanoparticles, uniformly laid on the crumpled graphene sheets and CNT. The as-prepared ZnO/graphene/CNT composite exhibited excellent cyclability and rate capability when used as anode for lithium ion batteries, affording 620 mAh g(-1) stable reversible discharge capacity after 100 cycles at 100 mA g(-1). The unique composite structure provided a large surface area and highly conductive network which maintains good electronic contact between particles, suppresses ZnO aggregation during the charge/discharge processes, and accommodates the large volume changes of ZnO upon cycling. (C) 2016 Elsevier B.V. All rights reserved.