• 文献标题:   Direct visualization of atomically precise nitrogen-doped graphene nanoribbons
  • 文献类型:   Article
  • 作  者:   ZHANG Y, ZHANG YF, LI G, LU JC, LIN X, DU SX, BERGER R, FENG XL, MULLEN K, GAO HJ
  • 作者关键词:  
  • 出版物名称:   APPLIED PHYSICS LETTERS
  • ISSN:   0003-6951 EI 1077-3118
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   49
  • DOI:   10.1063/1.4884359
  • 出版年:   2014

▎ 摘  要

We have fabricated atomically precise nitrogen-doped chevron-type graphene nanoribbons by using the on-surface synthesis technique combined with the nitrogen substitution of the precursors. Scanning tunneling microscopy and spectroscopy indicate that the well-defined nanoribbons tend to align with the neighbors side-by-side with a band gap of 1.02 eV, which is in good agreement with the density functional theory calculation result. The influence of the high precursor coverage on the quality of the nanoribbons is also studied. We find that graphene nanoribbons with sufficient aspect ratios can only be fabricated at sub-monolayer precursor coverage. This work provides a way to construct atomically precise nitrogen-doped graphene nanoribbons. (C) 2014 AIP Publishing LLC.