• 文献标题:   Germanium Nanoparticle-Dispersed Reduced Graphene Oxide Balls Synthesized by Spray Pyrolysis for Li-Ion Battery Anode
  • 文献类型:   Article
  • 作  者:   KIM JK, PARK GD, KANG YC
  • 作者关键词:   lithium ion batterie, germanium, graphene, carbon composite, spray pyrolysi
  • 出版物名称:   JOURNAL OF THE KOREAN CERAMIC SOCIETY
  • ISSN:   1229-7801 EI 2234-0491
  • 通讯作者地址:   Korea Univ
  • 被引频次:   3
  • DOI:   10.4191/kcers.2019.56.1.07
  • 出版年:   2019

▎ 摘  要

Simple fabrication of a powdered Ge-reduced graphene oxide (Ge-rGO) composite via spray pyrolysis and reduction is introduced herein. Successful incorporation of the rGO nanosheets with Ge hindered the aggregation of Ge and conferred enhanced structural stability to the composite by alleviating the mechanical stress associated with drastic volume changes during repeated cycling. The Li-ion storage performance of Ge-rGO was compared with that of powdered Ge metal. The reversible discharge capacity of Ge-rGO at the 200(th) cycle was 748 mA h g(-1) at a current density of 1.0 A g(-1) and Ge-rGO showed a capacity of 375 mA h g(-1) even at a high current density of 5.0 A g(-1). The excellent performance of Ge-rGO is attributed to the structural robustness, enhanced electrical conductivity, and formation of open channels between the rGO nanosheets, which facilitated electrolyte penetration for improved Li-ion diffusion.