• 文献标题:   1D/2D carbon nanotube/graphene nanosheet composite anodes fabricated using electrophoretic assembly
  • 文献类型:   Article
  • 作  者:   SEO SD, HWANG IS, LEE SH, SHIM HW, KIM DW
  • 作者关键词:   multiwalled carbon nanotube, graphene nanosheet, electrophoretic deposition, composite electrode, li ion batterie
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842
  • 通讯作者地址:   Ajou Univ
  • 被引频次:   34
  • DOI:   10.1016/j.ceramint.2011.11.083
  • 出版年:   2012

▎ 摘  要

This study examines the direct assembly of hybrid graphene nanosheets (GNSs) and multiwalled carbon nanotubes (MWCNTs) onto Ni current collectors in the presence of an electric field. The dissociation of Ni nitrate salt, which provides ions to charge the GNSs and MWCNTs positively, facilitates the homogeneous dispersion of each powder and assists in electrophoretic deposition. Direct assembly by this electrophoretic deposition results in the effective packing of GNS/MWCNT composites without any appreciable agglomeration, which is desirable for achieving high electrochemical performance of the composite electrodes in Li-ion batteries. Hence, GNS/MWCNT composite electrodes exhibit higher specific capacity compared to electrodes made of pure GNSs or MWCNTs owing to better realization of electrolyte permeability and Li-ion transfer. (C) 2011 Elsevier Ltd and Techna Group S.r.l. All rights reserved.