• 文献标题:   One-step synthesis of Au nanoparticle-graphene composites using tyrosine: electrocatalytic and catalytic properties
  • 文献类型:   Article
  • 作  者:   WANG Q, WANG Q, LI MS, SZUNERITS S, BOUKHERROUB R
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Univ Lille 1
  • 被引频次:   16
  • DOI:   10.1039/c5nj03532e
  • 出版年:   2016

▎ 摘  要

An easy and environmentally friendly method is described for the in situ synthesis of a reduced graphene oxide/gold nanoparticle (rGO/Au NPs) nanocomposite through the simultaneous reduction of GO and HAuCl4 using tyrosine in water. The rGO/Au NPs/Tyr nanocomposite has been characterized using different techniques such as UV-vis spectrometry, Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electrochemical measurements. The electrocatalytic and catalytic activities of the resulting hybrid nanomaterial have been investigated for the nonenzymatic electrochemical detection of hydrogen peroxide (H2O2) and nitrophenol reduction, respectively. The sensor displayed a detection limit of 20 mu M over a wide linear range from 0.02 to 25 mM with a sensitivity of 46.46 mM mM(-1) cm(-2). In addition, the sensor also showed good selectivity for H2O2 detection, long-term stability and reproducibility. Furthermore, the rGO/ Au NPs/Tyr nanocomposite exhibited good catalytic activity toward 4-nitrophenol reduction.