• 文献标题:   Preparation of CTAB-Assisted Hexagonal Platelet Co(OH)(2)/Graphene Hybrid Composite as Efficient Supercapacitor Electrode Material
  • 文献类型:   Article
  • 作  者:   GHOSH D, GIRI S, DAS CK
  • 作者关键词:   cobalt hydroxide, graphene, specific capacitance, supercapacitor
  • 出版物名称:   ACS SUSTAINABLE CHEMISTRY ENGINEERING
  • ISSN:   2168-0485
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   86
  • DOI:   10.1021/sc400055z
  • 出版年:   2013

▎ 摘  要

In this paper, our work deals with the preparation of cetyl trimethylammonium bromide (CTAB)assisted hexagonal platelet beta Co(OH)(2) via a simple hydrothermal process and its graphene-based hybrid composite with improved electrochemical properties. The prepared materials were successfully characterized by FTIR, XRD, FESEM, TEM, and TGA analysis. The materials were subjected to electrochemical analysis by a three electrode system in a 6 M KOH electrolyte in terms of a cyclic voltammetry, cyclic charge-discharge, and electrochemical impedance study. The CTAB-assisted Co(OH)(2) with hexagonal architecture exhibited the highest specific capacitance of 312 F/g at a 2 mV/s scan rate and 285 F/g at a 2 A/g constant discharge current density. The high utility of pseudocapacitive Co(OH)(2) is achieved only in its graphene-based hybrid composite, which responded with specific capacitance of 532 F/g at a 2A/g current density and a 94% specific capacitance retention over 500 charge discharge cycles.