▎ 摘　　要

Lignin is considered as a promising bio-sourced precursor for more sustainable and low-cost carbon fibers (CFs). However, lignin-based CFs generally have a poor graphitic structure, compared to polyacrylonitrile CFs. In this paper, we present an original approach that uses graphene oxide liquid crystal (GOLC) as a templating agent to promote the formation of graphitic structure in the fibers at low carbonization temperature. Both lignin and hybrid lignin/GOLC CFs were carbonized/graphitized up to 2700 degrees C. Structural analyses by X-ray diffraction, Raman spectroscopy and electrical measurements manifest a significant improvement in graphitic structure and a preferred orientation of graphene planes for lignin/GOLC fibers. These effects are the result of axial propagation of the templated graphitic order nucleated by the large GO flakes. The current approach reveals the possibility of preparing low-cost lignin-based CFs with improved graphitic structure and high electrical conductivity at low temperature for electrochemical or smart textile applications. (c) 2020 Elsevier Ltd. All rights reserved.