▎ 摘　　要

Graphene laminated (GL) coatings formed by stacked few layer graphene (FLG) nanocrystals were deposited on low-density polyethylene (PE) films by the mechanical rubbing technique. Molecular transport through the bilayer membrane was studied by the gas phase permeation technique by monitoring the CO2, N-2 and H-2(2) transport fluxes in transient conditions. The results evidenced that the transport exhibited anomalous character. The experimental data could be reproduced assuming that the penetrant concentration in the GL coating, c(int)(t), reached a saturation value c(s) following compressed exponential kinetics c(int)(t) = c(s)[1 - e(-(lambda relt)beta)]. The relaxation time tau(rel) = 1/lambda(rel) showed thermally activated behavior, and its value increased with the kinetic diameter of the penetrant molecules. The critical exponent beta = 1.5 +/- 0.1 for CO2 and N-2 and beta = 2.0 +/- 0.1 for H-2(2) did not change with temperature. Positron annihilation lifetime spectroscopy (PALS) analysis indicated that the average cross-section (h(g)) of the cavities in the GL coating exhibited comparable size to the kinetic diameter (sigma(k)) of the penetrant molecules. The results could be explained by assuming that the molecular infiltration in the GL structure occurred in nano-channels having distributed path lengths where the penetrant transport obeyed a configurational diffusion mechanism.