• 文献标题:   Clinically Pertinent Manganese Oxide/Polyoxytyramine/Reduced Graphene Oxide Nanocomposite for Voltammetric Detection of Salivary and Urinary Arsenic
  • 文献类型:   Article
  • 作  者:   PONNAIAH SK, PERIAKARUPPAN P, SELVAM M, MUTHUPANDIAN S, JEYAPRABHA B, SELVANATHAN R
  • 作者关键词:   nanocomposite, mno2, polyoxytyramine, rgo, voltammetry, arsenic quantification, saliva urine sample
  • 出版物名称:   JOURNAL OF CLUSTER SCIENCE
  • ISSN:   1040-7278 EI 1572-8862
  • 通讯作者地址:   Thiagarajar Coll
  • 被引频次:   2
  • DOI:   10.1007/s10876-019-01696-4 EA OCT 2019
  • 出版年:   2020

▎ 摘  要

Arsenic (As-III), a notorious environmental hazard poses threat to the lives of several hundred million people. Notwithstanding radical developments of As-III detection in water, a fast, simple and sensitive electrochemical process with lower detection limit for the quantification of As-III in saliva and urine samples has scarcely ever been tried. Here, we have detected the poisoning due to As-III in the saliva and urine samples of tobacco-chewers/smokers using a novel one-pot synthesized MnO2/polyoxytyramine/rGO nanocomposite. The composite was characterized by various analytical techniques such as UV-Vis. and FT-IR spectroscopic analyses, XRD, SEM, TEM, EDAX and elemental mapping analyses. The proposed As-III quantification system has a wide linearity range (0.01-0.900 ppb) and the lowest detection limit (42 parts per trillion).