• 文献标题:   Sonochemical synthesis and application of rhodium-graphene nanocomposite
  • 文献类型:   Article
  • 作  者:   CHANDRA S, BAG S, BHAR R, PRAMANIK P
  • 作者关键词:   graphene, rhodium nanoparticle, sonochemical, hydrogenation, nanomaterial
  • 出版物名称:   JOURNAL OF NANOPARTICLE RESEARCH
  • ISSN:   1388-0764 EI 1572-896X
  • 通讯作者地址:   Indian Inst Technol
  • 被引频次:   18
  • DOI:   10.1007/s11051-010-0164-3
  • 出版年:   2011

▎ 摘  要

Highly water dispersible rhodium-graphene nanocomposite have been successfully synthesized by the simple reduction of Rh3+ salt on poly(ethylene oxide)/poly(propylene oxide)/poly(ethylene oxide) (PEO/PPO/PEO) triblock copolymer or pluronic-stabilized graphene oxide (GO) nanosheets with borohydride. Rhodium nanoparticles, having average size of 1-3 nm, are homogeneously distributed through out the graphene sheets. Some porous structures of graphene sheets have also been observed after the reduction of pluronic-stabilized GO in the presence of metal ions. The material is very effective for hydrogenation of arenes, especially for benzene as the substrate material at the room temperature and 5 atm pressure of hydrogen.