▎ 摘　　要

Two vastly different types of load-displacement responses observed in graphitic nanostructures under nano-compression are compared in terms of serration behaviors. Different from commonly encountered linear/nonlinear elastic deformation, a periodic serration behavior related to plastic flow is observed in amorphous carbon nanospheres. The true stress-strain relation exhibits a sole feature of type C serration, and comprehensive statistical, dynamical and fractal analyses further demonstrate a chaotic characteristic of dynamics for those serration events. When entering a quasi-steady flow stage, the elastic stress in each serration event could maintain a relatively stable level near similar to 135 MPa, very close to the interlayer shear stress (ISS) of single crystalline graphite (similar to 140 MPa). This finding indicates the dependence of shear deformation on weak van der Waals interaction (elastic constant C-44), instead of other structural factors associated with high elastic constants of graphite cells. Based on the experimental results, a microscale ISS-driven shearing mechanism is proposed. The local flexibility induced by small graphene lamellas may facilitate interfacial slip between neighboring domains with commensurate contact. Such slip mode may be responsible for the mechanical serration phenomenon in graphitic materials. (C) 2018 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.