▎ 摘　　要

Nanostructuring and second phase incorporation are considered to be promising ways of enhancing the thermoelectric performance of bulk materials. Here, a design principle is proposed which combines these two methods for improving the thermoelectric performance of p-type CoSb3 by fabricating a CoSb3/graphene (CoSb3/G) nanocomposite, where a second phase, graphene, is introduced in the nanostructured CoSb3 matrix via an in situ one-pot solvothermal route. In addition, CoSb3/G bulk materials were prepared by hot pressing the solvothermally synthesized CoSb3/G powder. It was found that addition of a small amount of graphene can drastically enhance the electrical conductivity due to the increase in both carrier concentration and mobility. In addition, the well dispersed graphene in the nanostructured CoSb3 matrix also contributes to the low lattice thermal conductivity. A dimensionless figure of merit ZT = 0.61 at 800 K has been obtained for the CoSb3/G nanocomposite, which is about a 130% improvement over that of graphene-free CoSb3 (similar to 0.26).