▎ 摘 要
An efficient adsorbent to remove Pb(ii) from water was prepared by treating polydimethylsiloxane (PDMS) sponge with polyvinyl alcohol and then coating the sponge with graphene oxide (GO). The GO-PDMS sponge was highly hydrophilic, easily handled during and after use, and easily recycled. The kinetics and isotherms of Pb(ii) sorption onto the GO-PDMS sponge were investigated by performing batch sorption tests. The kinetics of Pb(ii) sorption onto the GO-PDMS sponge indicated that sorption equilibrium occurred rapidly (within 60 min) and that the sorption data could be described using a pseudo-second-order model. Maximum Pb(ii) sorption onto the GO-PDMS sponge occurred at pH > 5. Increasing GO loading on the PDMS sponge increased the amount of Pb(ii) that could be sorbed. The isotherm for Pb(ii) sorption onto the GO-PDMS sponge was non-linear and was well described by the Langmuir isotherm model, indicating that Pb(ii) sorption onto the GO-PDMS sponge was homogeneous and occurred through sorption of a monolayer of Pb(ii). The GO-PDMS sponge, used as a filter, removed Pb(ii) efficiently from water. The Pb(ii) removal efficiencies were more than 50% and the maximum was 85%.