• 文献标题:   Carbon-wrapped MnO nanodendrites interspersed on reduced graphene oxide sheets as anode materials for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LIU BL, LI D, LIU ZJ, GU LL, XIE WH, LI Q, GUO PQ, LIU DQ, HE DY
  • 作者关键词:   lithiumion battery, carbonwrapped mno nanodendrite, reduced graphene oxide
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Lanzhou Univ
  • 被引频次:   24
  • DOI:   10.1016/j.apsusc.2016.10.108
  • 出版年:   2017

▎ 摘  要

Carbon-wrapped MnO nanodendrites interspersed on reduced graphene oxide sheets (C-MnO/rGO) were prepared on nickel foam by a facile vacuum filtration and a subsequent thermal treatment. As a binder-free anode of lithium-ion battery, the nanodendritic structure of C-MnO accommodates the huge volume expansion and shortens the diffusion length for lithium ion and electron, rGO sheets prevent C-MnO nanodendites from aggregation and offer a good electronic conduction. As a result, the electrode with such a novel architecture delivers superior electrochemical properties including high reversible capacity, excellent rate capability and cycle stability. Moreover, MnO nanodendrites change to nanoparticles wrapped in graphene sheets during the lithiation/delithiation process, which is a more beneficial microstructure to further increase the specific capacity and cycle life of the electrode. (C) 2016 Elsevier B.V. All rights reserved.