• 文献标题:   Mildly reduced less defective graphene oxide/sulfur/carbon nanotube composite films for high-performance lithium-sulfur batteries
  • 文献类型:   Article
  • 作  者:   LI R, ZHANG M, LI YR, CHEN J, YAO BW, YU MP, SHI GQ
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Tsinghua Univ
  • 被引频次:   21
  • DOI:   10.1039/c6cp00512h
  • 出版年:   2016

▎ 摘  要

The microstructures and properties of the carbonaceous matrices in the cathodes of lithium-sulfur (Li-S) batteries have strong effects on their performances. We prepared a ternary composite cathode of mildly reduced less defective graphene oxide (mrLGO), sulfur, and carbon nanotubes (CNTs) by filtration for Li-S batteries. This battery showed a high initial specific capacity of 1219 mA h g(-1) at 0.2 C and a stable specific capacity of around 1000 mA h g(-1) after 200 cycles with a coulombic efficiency of 99%. Its excellent performance is mainly attributed to the good conductivity and residual oxygen containing groups of mrLGO, and the three-dimensional (3D) framework constructed using mrLGO sheets and CNTs.