• 文献标题:   Determination of Gallic Acid in Tea by a Graphene Modified Glassy Carbon Electrode
  • 文献类型:   Article
  • 作  者:   CHEN MF, LV HP, LI X, TIAN ZL, MA XY
  • 作者关键词:   gallic acid, differential pulse voltammetry, graphene, electrochemical determination
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Heze Univ
  • 被引频次:   2
  • DOI:   10.20964/2019.05.23
  • 出版年:   2019

▎ 摘  要

The determination of gallic acid (GA) content by a graphene modified glassy carbon electrode (graphene/GCE) was studied. The electrochemical behavior of GA on this electrode was studied by cyclic voltammetry (CV), and the standard curve was constructed by differential pulse voltammetry (DPV). The results indicate that graphene has a good catalytic effect on GA in phosphate buffer (PBS) and shows a linear response toward GA in the 8.0 x 10(-8) to 2.0 x 10(-5) mol.L-1 concentration range. The detection limit is 1.2 x 10(-9) mol.L-1. This proposed determination for GA on graphene/GCE was carried out in the presence of potentially interfering compounds such as sorbic acid, tartaric acid, ascorbic acid and glucose. The content of GA in green tea was determined by this method, and the recovery was 97.9% - 100.6% with satisfactory results.