• 文献标题:   Free-standing, flexible beta-Ni(OH)(2)/electrochemically-exfoliated graphene film electrode for efficient oxygen evolution
  • 文献类型:   Article
  • 作  者:   WANG LL, ZHANG J, JIANG WT, ZHAO H, LIU HZ
  • 作者关键词:   water oxidation, nickel hydroxide, graphene, film electrode, freestanding, flexible
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Tech Univ Dresden
  • 被引频次:   5
  • DOI:   10.1016/j.apsusc.2017.09.196
  • 出版年:   2018

▎ 摘  要

The oxidation of water into molecular oxygen (oxygen evolution reaction, OER) is a pivotal reaction in many energy conversion devices. The high cost of IrO2, however, seriously hinder its large-scale applications in water oxidation. Here, we have at first reported a free-standing and flexible film electrode consisting of 2D beta-Ni(OH)(2)/electrochemically-exfoliated graphene hybrid nanosheets (NiG-2), which is synthesized by a solvothermal reaction and an assembly process. The as-obtained NiG-2 film electrode exhibited an excellent electrocatalytic OER activity with an extremely low OER onset overpotential of similar to 250 mV in a 1 M KOH aqueous solution, which is lower than these of the commercial Ir/C (370 mV at 10 mA cm(-2)) catalyst. (C) 2017 Elsevier B.V. All rights reserved.