• 文献标题:   Highly uniform Co9S8 nanoparticles grown on graphene nanosheets as advanced anode materials for improved Li-storage performance
  • 文献类型:   Article
  • 作  者:   LIU SM, WANG JX, WANG JW, ZHANG FF, WANG LM
  • 作者关键词:   co9s8, graphene nanosheet, nanocomposite, anode, lithium ion battery
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   8
  • DOI:   10.1016/j.apsusc.2016.08.092
  • 出版年:   2016

▎ 摘  要

A Co9S8/GNS (graphene nanosheets) nanocomposites has been synthesized via a facile solvothermal approach followed by thermal treatment in nitrogen at 500 degrees C using graphite oxide sheets, CoCl2 center dot 6H(2)O and thiourea as the starting materials. Highly uniform Co9S8 nanoparticles with a size of about 80-90 nm are evenly grafted on the surface of GNS, forming a unique Co9S8/GNS hybrid nanostructure. When evaluated as anode materials for lithium ion batteries, impressive electrochemical performances of the as-prepared nanocomposites are achieved compared to that of pure bulk Co9S8, with an high reversible capacity of 1480 mAh g(-1). Moreover, the as-synthesized nanocomposites present excellent cycling durability and high-rate capability. The improvement in the electrochemical properties could be attributed to the well-designed structure of the Co9S8/GNS nanocomposite which possesses large number of accessible active sites for lithium-ion insertion, fast ion diffusion rate and good electronic conductivity. (C) 2016 Elsevier B.V. All rights reserved.