▎ 摘 要
A Co9S8/GNS (graphene nanosheets) nanocomposites has been synthesized via a facile solvothermal approach followed by thermal treatment in nitrogen at 500 degrees C using graphite oxide sheets, CoCl2 center dot 6H(2)O and thiourea as the starting materials. Highly uniform Co9S8 nanoparticles with a size of about 80-90 nm are evenly grafted on the surface of GNS, forming a unique Co9S8/GNS hybrid nanostructure. When evaluated as anode materials for lithium ion batteries, impressive electrochemical performances of the as-prepared nanocomposites are achieved compared to that of pure bulk Co9S8, with an high reversible capacity of 1480 mAh g(-1). Moreover, the as-synthesized nanocomposites present excellent cycling durability and high-rate capability. The improvement in the electrochemical properties could be attributed to the well-designed structure of the Co9S8/GNS nanocomposite which possesses large number of accessible active sites for lithium-ion insertion, fast ion diffusion rate and good electronic conductivity. (C) 2016 Elsevier B.V. All rights reserved.