• 文献标题:   Electrically-doped CVD-graphene transparent electrodes: application in 365 nm light-emitting diodes
  • 文献类型:   Article
  • 作  者:   CHAE MS, LEE TH, SON KR, KIM YW, HWANG KS, KIM TG
  • 作者关键词:  
  • 出版物名称:   NANOSCALE HORIZONS
  • ISSN:   2055-6756 EI 2055-6764
  • 通讯作者地址:   Korea Univ
  • 被引频次:   7
  • DOI:   10.1039/c8nh00374b
  • 出版年:   2019

▎ 摘  要

Electric-field-induced doping treatment is applied to a monolayer graphene (MLG) film to improve its usability as a transparent conductive electrode (TCE). Ni is used as a doping source, which produces conductive bridges consisting of ionized Ni by electromigration from an Ni pad to the as-transferred chemical vapor deposition grown MLG films through AlN buffer layers, by applying voltages of 3.62 +/- 0.34 V. As a result, the sheet resistance of the MLG reduces from 712 +/- 75.2 X sq(-1) to 216 +/- 46.1 X sq(-1) and the surface current increases from 6.63 +/- 2.07 nA to 8.91 +/- 1.62 nA. Additionally, the work function of the MLG increases from 4.36 eV to 5.0 eV due to p-type doping effects. The intercalation of Ni atoms into the MLG is directly confirmed by X-ray photoelectron spectroscopy and Raman spectrum analyses. Finally, the Ni-doped MLG is utilized as the TCE layer for 365 nm light-emitting diodes, exhibiting much better optical properties compared to a standard LED with a 100 nm-thick indium tin oxide electrode.