• 文献标题:   Enhanced Biosensing of Bisphenol A Using a Nanointerface Based on Tyrosinase/Reduced Graphene Oxides Functionalized with Ionic Liquid
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   LI R, WANG YY, DENG YH, LIU GS, HOU XD, HUANG Y, LI CY
  • 作者关键词:   reduced graphene oxide, ionic liquid, tyrosinase, electrochemical sensor, bisphenol a
  • 出版物名称:   ELECTROANALYSIS
  • ISSN:   1040-0397 EI 1521-4109
  • 通讯作者地址:   South Cent Univ Nationalities
  • 被引频次:   7
  • DOI:   10.1002/elan.201500448
  • 出版年:   2016

▎ 摘  要

Reduced graphene oxide (rGO) nanosheets functionalized with 1,3-di(4-amino-1-pyridinium) propane tetrafluoroborate ionic liquid (DAPPT) was successfully synthesized and fully characterized. DAPPT-rGO nanosheets were coated to a glassy carbon electrode (GCE) surface to immobilize tyrosinase (Tyr). The Tyr-DAPPT-rGO/GCE was characterized with scanning electronic microscopy and electrochemical impedance spectroscopy. The biosensor shows a linear response to bisphenol A (BPA) in the concentration range of 1.0x10(-9)approximate to 3.8x10(-5)molL(-1). The detection limit was calculated to be 3.5x10(-10)molL(-1) (S/N=3). The practical application was demonstrated by determining BPA leaching from commercial plastic drinking bottles.