• 文献标题:   Microwave synthesis of three dimensional N-doped graphene self-supporting networks coated with Zinc/Nickel oxide nanocrystals for supercapacitor electrode applications
  • 文献类型:   Article
  • 作  者:   ZHANG MM, MA TJ, WANG Y, PAN DH, XIE JM
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS SCIENCEMATERIALS IN ELECTRONICS
  • ISSN:   0957-4522 EI 1573-482X
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   6
  • DOI:   10.1007/s10854-018-8686-z
  • 出版年:   2018

▎ 摘  要

A hybrid of zinc/nickel oxide nanoparticles supported on nitrogen doped three-dimensional graphene networks (ZnO/NiO/3DNG) have been designed through a simple microwave process assisted tube furnace thermal treatment. Well dispersed coupled zinc/nickel oxides nanoparticles with sizes of 10-20 nm are homogeneously anchored on 3DNG hybrid structure. As electrode active material of supercapacitors, the ZnO/NiO/3DNG nanocomposites exhibits an ultrahigh specific capacitance of 1839.4 F g(-1) at a current density of l A g(-1) in 6.0 M KOH solution, the EIS analysis of the electrode after 6000th cycle at 10 A g(-1) remained about 93%, displayed that the fitting values of inner resistance and faradic charge transfer resistance of the electrode are low and electrode activity don't change too much after cycling. Furthermore, the ZnO/NiO/3DNG composites exhibits the maximum energy density of 35.32 Wh kg(-1) with the power density 139.72 W kg(-1) at high current density of 10 A g(-1) in the two-electrode system. The outstanding performance originates from the flexible three dimensional N-doped unique structural, which play important roles in stabilizing ZnO and NiO.