• 文献标题:   Designing versatile heterogeneous catalysts based on Ag and Au nanoparticles decorated on chitosan functionalized graphene oxide
  • 文献类型:   Article
  • 作  者:   RAJESH R, SUJANTHI E, KUMAR SS, VENKATESAN R
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   VIT Univ
  • 被引频次:   43
  • DOI:   10.1039/c5cp00682a
  • 出版年:   2015

▎ 摘  要

Herein we report the covalent grafting of chitosan on graphene oxide (GO) followed by a simple approach for anchoring silver (AgNPs) and gold (AuNPs) nanoparticles onto a chitosan grafted graphene oxide surface by a NaBH4 reduction method. Catalytic activity of prepared heterogeneous GO grafted chitosan stabilized silver and gold nanocatalysts (GO-Chit-Ag/AuNPs) was explored for the reduction of aromatic nitroarenes and degradation of hazardous azo dyes in the presence of NaBH4. Both catalysts were found to exhibit excellent catalytic activity towards the reduction of aromatic nitroarenes and azo dyes degradation. Furthermore, the nanocatalysts were found to be selective towards the reduction of nitro groups in halonitroarenes without any dehalogenation under mild conditions.