• 文献标题:   A novel, eco-friendly technique for covalent functionalization of graphene nanoplatelets and the potential of their nanofluids for heat transfer applications
  • 文献类型:   Article
  • 作  者:   SADRI R, HOSSEINI M, KAZI SN, BAGHERI S, ZUBIR N, AHMADI G, DAHARI M, ZAHARINIE T
  • 作者关键词:   green functionalization, graphene nanoplatelets gnps, ecofriendly synthesi, thermal conductivity, nanofluid
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Univ Malaya
  • 被引频次:   16
  • DOI:   10.1016/j.cplett.2017.02.077
  • 出版年:   2017

▎ 摘  要

In this study, a facile and eco-friendly covalent functionalization technique is developed to synthesize highly stable graphene nanoplatelets (GNPs) in aqueous media. This technique involves free radical grafting of gallic acid onto the surface of GNPs rather than corrosive inorganic acids. Raman spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscopy are used to confirm the covalent functionalization of GNPs with gallic acid (GAGNPs). The solubility of the GAGNPs in aqueous media is verified using zeta potential and UV-vis spectra measurements. The nanofluid shows significant improvement in thermo-physical properties, indicating its superb potential for various thermal applications. (C) 2017 Elsevier B.V. All rights reserved.