• 文献标题:   Highly electrocatalytic hybrid silver nanowire-graphene counter electrode for Co3+/2+ redox mediator based dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   ALMAMUN M, KIM JY, LEE KJ, KO YH, LEE JH, IN IS, LEE JW, SUNG YE, KIM SR
  • 作者关键词:   silver nanowire, graphene platelet, counter electrode, cyclic voltammetry, dyesensitized solar cell
  • 出版物名称:   SYNTHETIC METALS
  • ISSN:   0379-6779
  • 通讯作者地址:   Korea Natl Univ Transportat
  • 被引频次:   8
  • DOI:   10.1016/j.synthmet.2013.06.010
  • 出版年:   2013

▎ 摘  要

Solution processed hybrid silver nanowire (AgNW)-graphene nanoplatelets (GNP) films were prepared and the electrocatalytic activity for the cobalt redox electrolyte in dye-sensitized solar cells (DSSCs) was examined. Cyclic voltammograms and Tafel polarization measurements confirmed the superior electrocatalytic activity of AgNW-GNP electrode than that of standard Pt counter electrode (CE). Electrochemical impedance spectroscopic (EIS) study also revealed the lower charge transfer resistance (R-ct) of AgNW-GNP compared to Pt based CE. However, the resistance of the electrolyte diffusion was higher for the AgNW-GNP based CE resulted from the porous structure of the hybrid CE. The photoconversion efficiencies of the DSSC prepared with AgNW-GNP based CE was found to be 2.44%, which was comparable to that of Pt based DSSC, 2.55%. This study proposed an alternative low-cost cathode material for the cobalt redox mediator based DSSCs. (C) 2013 Elsevier B.V. All rights reserved.