• 文献标题:   Pulse electrodeposition of Pt nanocatalysts on graphene-based electrodes for proton exchange membrane fuel cells
  • 文献类型:   Article
  • 作  者:   HSIEH CT, WEI JM, LIN JS, CHEN WY
  • 作者关键词:   pt catalyst, pulse electrodeposition, graphene oxide, carbon paper, fuel cell
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Yuan Ze Univ
  • 被引频次:   24
  • DOI:   10.1016/j.catcom.2011.09.030
  • 出版年:   2011

▎ 摘  要

Pulse electrodeposition of Pt nanocluster catalysts on graphene oxide (GO)-carbon paper composite electrode for proton exchange membrane fuel cells has been investigated. The primary particle size was found to be 100-300 nm for the urchin-like cluster that was composed of a number of secondary grains. Experimental results show that the GO sheets decorated with the Pt clusters displays low-equivalent series resistance (-2.60 Omega) and high-power density (-1.3 kW g(-1) at 60 degrees C). Hence, such a catalyst electrode, consisting of the GO sheets and the metallic Pt clusters, is proved to have several advantages such as good dispersion of catalysts and high catalytic activity. (C) 2011 Elsevier B.V. All rights reserved.