• 文献标题:   One-step hydrothermal synthesis of MoNiCoS nanocomposite hybridized with graphene oxide as a high-performance nanocatalyst toward methanol oxidation
  • 文献类型:   Article
  • 作  者:   ASKARI MB, SEIFI M, ROZATI SM, BEHESHTIMARNANI A, ZADEH MHR
  • 作者关键词:   methanol oxidation, direct methanol fuel cell, monicos, graphene, nanocatalyst
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   Univ Guilan
  • 被引频次:   2
  • DOI:   10.1016/j.cplett.2018.05.066
  • 出版年:   2018

▎ 摘  要

A carbon based nanocatalyst in the form of graphene hybridized MoNiCoS (MoNiCoS/Go) was synthesized in a single step hydrothermal method for methanol oxidation in a direct methanol fuel cell, as a substitution for expensive and rare platinum. The results obtained from methanol oxidation over the graphene hybridized MoNiCoS modified electrode revealed suitable electrocatalytic properties and a considerable diffusion current, confirmed by the Tafel plots through calculating the exchange current (io) as an important kinetic parameter of electron transfer. It was found that the above composite could be an appropriate alternative in designing a DMFC fuel cell as a clean energy generator. (C) 2018 Elsevier B.V. All rights reserved.