• 文献标题:   Insulator to Semimetal Transition in Graphene Oxide
  • 文献类型:   Article
  • 作  者:   EDA G, MATTEVI C, YAMAGUCHI H, KIM H, CHHOWALLA M
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF PHYSICAL CHEMISTRY C
  • ISSN:   1932-7447 EI 1932-7455
  • 通讯作者地址:   Rutgers State Univ
  • 被引频次:   414
  • DOI:   10.1021/jp9051402
  • 出版年:   2009

▎ 摘  要

Transport properties of progressively reduced graphene oxide (GO) are described. Evolution of the electronic properties reveals that as-synthesized GO undergoes insulator-semiconductor-semi metal transitions with reduction. The apparent transport gap ranges from 10 to 50 meV and approaches zero with extensive reduction. Measurements at varying degrees of reduction reveal that transport in reduced GO occurs via variable-range hopping and further reduction leads to an increased number of available hopping sites.