• 文献标题:   Grafted Carbazole-Assisted Electrodeposition of Graphene Oxide
  • 文献类型:   Article
  • 作  者:   MANGADLAO JD, DE LEON AC, FELIPE MJL, CAO PF, ADVINCULA PA, ADVINCULA RC
  • 作者关键词:   graphene oxide, electrodeposition, carbazole, electropolymerization, corrosion
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Case Western Reserve Univ
  • 被引频次:   15
  • DOI:   10.1021/acsami.5b00857
  • 出版年:   2015

▎ 摘  要

The electrodeposition of graphene oxide (GO) by covalently linked electroactive :monomer, carbazole (Cbz) is first demonstrated herein. This is based on the electropolyrnerization and electiodeposition of covakntly linked Cbz units when a potential is applied. During the electrochemical process, the Cbz groups electropolymerize and carry the GO nanosheets as it electiodeposits on the substrate. Moreover, the GO-Cbz sheets selectively deposit onto the conducting regions of the substrate, which demonstrates its promise for the fabrication of electropattemed graphene-based devces. In addition, GO-Cbz is a promising material for the fabrication of nanocomposite Coatings for anticorrosion application. In as little as 1 wt % GO-Cbtz loacling, a protection efficiency as high as 95.4% was achieved.