• 文献标题:   Interconnectivity of Macroporous Hydrogels Prepared via Graphene Oxide-Stabilized Pickering High Internal Phase Emulsions
  • 文献类型:   Article
  • 作  者:   YI WY, WU H, WANG HT, DU QG
  • 作者关键词:  
  • 出版物名称:   LANGMUIR
  • ISSN:   0743-7463
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   57
  • DOI:   10.1021/acs.langmuir.5b04477
  • 出版年:   2016

▎ 摘  要

Interconnected macroporous poly(acrylic acid) (PAA) hydro gels are prepared via oil-in-water (o/w) Pickering high internal phase emulsion (RIPE) templates stabilized by graphene oxide (GO). The amphiphilicity of GO is adjusted by slight modification with cetyltrimethylammonium bromide (CTAB). The morphology of macroporous PAA is observed by a field-emission scanning electron microscope (FE-SEM). The gas permeability is characterized to evaluate the interconnectivity of polymer foams. The pore and pore throat size can be tailored by varying the wettability and concentration of GO. The selective adsorption toward dyes of PAA hydrogels is proved. Macroporous PAA hydrogels with an open-cell structure show enhanced adsorption behavior of both methylene blue (MB) and copper(II) ions.