▎ 摘　　要

We report a novel monolithic porous carbon constructed by the hydrothermal self-assembly of graphene oxide sheets with poly (vinyl alcohol) as the linker in the formation process of a three-dimensional (3D) structure. All the pores in this carbon have circular cross-sections and range from micropores to mesopores to macropores and are formed by the gradual removal of trapped water. This 3D graphene network together with unique spheroidal and hierarchical pore structure with macropore openings at the surface allows fast ion and electron transport into the innermost micropores. The carbon not only exhibits excellent capability for removal of dye pollutants and oils but also shows a good performance as an electrode material in lithium ion batteries. Moreover, it is also proved to be an ideal buffer for expanded active materials in electrochemical energy storage. (C) 2013 Elsevier Ltd. All rights reserved.