• 文献标题:   A Flexible Method for Covalent Double Functionalization of Graphene Oxide
  • 文献类型:   Article
  • 作  者:   GUO S, NISHINA Y, BIANCO A, MENARDMOYON C
  • 作者关键词:   graphene, materials science, michael addition, small ring system, surface chemistry
  • 出版物名称:   ANGEWANDTE CHEMIEINTERNATIONAL EDITION
  • ISSN:   1433-7851 EI 1521-3773
  • 通讯作者地址:   Univ Strasbourg
  • 被引频次:   11
  • DOI:   10.1002/anie.201913461 EA DEC 2019
  • 出版年:   2020

▎ 摘  要

A method for the double functionalization of graphene oxide (GO) under mild alkaline conditions has been developed. Two functional groups were covalently linked to GO in two steps: the first group was attached by an epoxide ring-opening reaction and the second, bearing an amine function, was covalently conjugated to benzoquinone attached to the GO. The doubly functionalized GO was characterized by several techniques, confirming the sequential covalent modification of the GO surface with two different functional groups. This method is straightforward and the reaction conditions are mild, allowing preservation of the structure and properties of GO. This strategy could be exploited to prepare multifunctional GO conjugates with potential applications in many fields ranging from materials science to biomedicine.