▎ 摘 要
Even though graphene is a low-energy system consisting of a two-dimensional honeycomb lattice of carbon atoms, its quasiparticle excitations are fully described by the (2+1)-dimensional relativistic Dirac equation. In this paper we show that, while the spin-orbit interaction in graphene is of the order of 4 meV, it opens up a gap of the order of 10(-3) meV at the Dirac points. We present a first-principles calculation of the spin-orbit gap, and explain the behavior in terms of a simple tight-binding model. Our result also shows that the recently predicted quantum spin Hall effect in graphene can occur only at unrealistically low temperature.