• 文献标题:   Optical and electrical properties of poly (N-vinylcarbazole)/graphene oxide nanocomposites for organic semiconductor devices
  • 文献类型:   Article
  • 作  者:   GOUMRI M, HATEL R, RATIER B, BAITOUL M
  • 作者关键词:   poly nvinylcarbazole, graphene oxide, semiconducting polymer, charge transport, photoluminescence
  • 出版物名称:   APPLIED PHYSICS AMATERIALS SCIENCE PROCESSING
  • ISSN:   0947-8396 EI 1432-0630
  • 通讯作者地址:   Univ Sidi Mohammed Ben Abdellah
  • 被引频次:   0
  • DOI:   10.1007/s00339-020-03812-y
  • 出版年:   2020

▎ 摘  要

In this work, organic semiconductor devices (OSD) incorporating both poly(N-vinylcarbazole) (PVK) and graphene oxide (GO) were fabricated. The stable solutions of PVK/GO were prepared in chloroform by a simple sonication method, which enabled the successful dispersion of GO with the polymer matrix. These nanomaterials have been used in the fabrication of OSD with configuration ITO/PVK:GO/Ag. The electrical and optical properties were investigated using several techniques. The electrical measurements show that the electrical behavior of PVK polymer enhanced with increasing GO nanofillers concentration. The observed electrical improvement in the nanocomposites can be attributed to the charge transfer interaction between carbazole electron donor and the functional groups onto the surface of GO. UV-Vis absorption and photoluminescence studies elucidated the energy transfer and the interaction between polymer chains and the graphene nanosheets which exhibit a strong blue-green luminescence.