• 文献标题:   Growth of III-N/graphene heterostructures in single vapor phase epitaxial process
  • 文献类型:   Article
  • 作  者:   LUNDIN WV, ZAVARIN EE, SAKHAROV AV, ZAKHEIM DA, DAVYDOV VY, SMIRNOV AN, ELISEYEV IA, YAGOVKINA MA, BRUNKOV PN, LUNDINA EY, MARKOV LK, TSATSULNIKOV AF
  • 作者关键词:   metalorganic vapor phase epitaxy, nanomaterial, nitride, semiconducting gallium compound
  • 出版物名称:   JOURNAL OF CRYSTAL GROWTH
  • ISSN:   0022-0248 EI 1873-5002
  • 通讯作者地址:   Ioffe Inst
  • 被引频次:   2
  • DOI:   10.1016/j.jcrysgro.2018.09.017
  • 出版年:   2018

▎ 摘  要

We investigated the growth of III-N/graphene heterostructures as a single process in a MOVPE reactor. Raman spectra revealed that graphene can be successfully deposited on sapphire substrate by propane pyrolysis if temperature exceeds 1060 degrees C and hydrogen is used as a carrier gas. GaN epitaxial layers and heterostructures on such graphene using both high-temperature AlN buffer layer and low-temperature GaN nucleation layer was demonstrated. Analysis of surface morphology and X-Ray diffraction curves indicate that GaN quality depends on graphene thickness. Use of copper electroplated Ni-based contact layer combined with thermal shock allows exfoliation of large-area III-N LED structures from sapphire.