• 文献标题:   Fabrication of c-axis oriented Si3N4 ceramics using multilayered-graphene-coated beta-Si3N4 seeds and their orientation in an innovative low magnetic field
  • 文献类型:   Article
  • 作  者:   TAKAHASHI T, SADO M, SUGIMOTO N, TATAMI J, IIJIMA M, INAGAKI S, KUBOTA Y, YAMAMOTO I, TANAKA S
  • 作者关键词:   silicon nitride, magnetic field orientation, graphene, thermal conductivity
  • 出版物名称:   ADVANCED POWDER TECHNOLOGY
  • ISSN:   0921-8831 EI 1568-5527
  • 通讯作者地址:   Kanagawa Acad Sci Technol
  • 被引频次:   5
  • DOI:   10.1016/j.apt.2016.07.006
  • 出版年:   2016

▎ 摘  要

c-axis oriented Si3N4 ceramics were fabricated by applying a low static magnetic field. Conventionally, c-axis oriented Si3N4 ceramics are fabricated using a rotating magnetic field of over 10 T considering the anisotropy and the magnitude of diamagnetic susceptibility between c- and a-axes. In this work, multilayered-graphene was used for orienting rod-like beta-Si3N4 particles as graphene exhibits a high diamagnetic anisotropy. The multilayered-graphene was coated with their orientation on the surface of rod-like beta-Si3N4 particles by using a mechanical treatment process. As a result, the c-axis of multilayered-graphene-coated beta-Si3N4 particles were oriented parallel direction to the applied magnetic field even at 0.4 T. In addition, c-axis oriented Si3N4 ceramics were fabricated successfully by adding a small quantity of multilayered-graphene-coated B-Si3N4 particles as seeds. The thermal conductivity of the c-axis oriented Si3N4 ceramics prepared with a magnetic field of 0.4 T exhibited anisotropy with a higher value achieved in the c-axis oriented direction. (C) 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.