• 文献标题:   Amino acids functionalized graphene oxide for enhanced hydrophilicity and antifouling property of poly(vinylidene fluoride) membranes
  • 文献类型:   Article
  • 作  者:   LI JH, WANG SS, ZHANG DB, NI XX, ZHANG QQ
  • 作者关键词:   pvdf membrane, graphene oxide, amino acid, hydrophilicity, antifouling property
  • 出版物名称:   CHINESE JOURNAL OF POLYMER SCIENCE
  • ISSN:   0256-7679 EI 1439-6203
  • 通讯作者地址:   Fuzhou Univ
  • 被引频次:   13
  • DOI:   10.1007/s10118-016-1808-2
  • 出版年:   2016

▎ 摘  要

Herein, functionalized graphene oxide (GO) was prepared by the covalent functionalization with amino acids (lysine, glycine, glutamic acid and tyrosine) in this study. Zeta potential results demonstrated that covalent functionalization of GO with amino acids was favourable for their homogeneous dispersion in water and organic solvents. Based on the higher absolute value of zeta potential and the better dipersion stability of GO-lysine, the PVDF/GO-lysine hybrid membranes were then prepared via the phase inversion induced by immersion precipitation technique. SEM images showed a better pore diameter and porosity distribution on the PVDF/GO-lysine membrane surface. The zeta potential absolute value of the PVDF/GO-lysine membrane surface was higher than that of the virgin PVDF membrane. Furthermore, the PVDF/GO-lysine membranes surface exhibited good hydrophilicity. The water flux of PVDF/GO-lysine membranes can reach to two times of that of the virgin PVDF membrane. And the BSA adsorbed amount on PVDF/GO-lysine surface was decreased to 0.82 mg/cm(2) for PVDF/GO-lysine-8% membrane. Filtration experiment results indicated that the fouling resistance was significantly improved for the PVDF/GO-lysine membranes. As a result, lysine functionalized GO will provide a promising method to fabricate graphene oxide based hybrid membranes with effective antifouling property and hydrophilicity.