• 文献标题:   One-Step Synthesis of Diamine-Functionalized Graphene Quantum Dots from Graphene Oxide and Their Chelating and Antioxidant Activities
  • 文献类型:   Article
  • 作  者:   ELHNAYN R, CANABADYROCHELLE L, DESMARETS C, BALAN L, RINNERT H, JOUBERT O, MEDJAHDI G, BEN OUADA H, SCHNEIDER R
  • 作者关键词:   graphene quantum dot, 2, 2 ethylenedioxy bis ethylamine, optical propertie, redoxactive nanoparticle
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:   Univ Lorraine
  • 被引频次:   7
  • DOI:   10.3390/nano10010104
  • 出版年:   2020

▎ 摘  要

2,2'-(Ethylenedioxy)bis(ethylamine)-functionalized graphene quantum dots (GQDs) were prepared under mild conditions from graphene oxide (GO) via oxidative fragmentation. The as-prepared GQDs have an average diameter of ca. 4 nm, possess good colloidal stability, and emit strong green-yellow light with a photoluminescence (PL) quantum yield of 22% upon excitation at 375 nm. We also demonstrated that the GQDs exhibit high photostability and the PL intensity is poorly affected while tuning the pH from 1 to 8. Finally, GQDs can be used to chelate Fe(II) and Cu(II) cations, scavenge radicals, and reduce Fe(III) into Fe(II). These chelating and reducing properties that associate to the low cytotoxicity of GQDs show that these nanoparticles are of high interest as antioxidants for health applications.